https://doi.org/10.1140/epjs/s11734-025-02063-3
Regular Article
Quantum defects of Rydberg excitons in cuprous oxide: a semiclassical spherical model
Institut für Theoretische Physik I, Universität Stuttgart, 70550, Stuttgart, Germany
a
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Received:
26
March
2025
Accepted:
9
November
2025
Published online:
15
November
2025
Abstract
Excitons, i.e., the bound states of an electron and a positively charged hole, are the solid-state analog of the hydrogen atom. As such, they exhibit a Rydberg series, which in cuprous oxide has been observed up to high principal quantum numbers by Kazimierczuk et al. (Nature 514:343–347, 2014. https://doi.org/10.1038/nature13832). In this energy regime, the quantum mechanical properties of the system can be understood in terms of classical orbits by the application of semiclassical techniques. In fact, the first theoretical explanation of the spectrum of the hydrogen atom within Bohr’s atomic model was a semiclassical one using classical orbits and a quantization condition for the angular momentum. Contrary to the hydrogen atom, the degeneracy of states with the same principal quantum number n is lifted in exciton spectra. This is similar to the situation in alkali atoms, where these splittings are caused by the interaction of the excited electron with the ionic core. For excitons in cuprous oxide, these splittings occur due to the influence of the complex band structure of the crystal. Using an adiabatic approach and analytically derived energy surfaces, we develop a semiclassical spherical model and determine, via semiclassical torus quantization, the quantum defects of various angular momentum states.
© The Author(s) 2025
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