https://doi.org/10.1140/epjs/s11734-023-00944-z
Regular Article
Quantum study of the radiative association of Cl
and Cl
1
Chemistry Department, Queen’s University, K7L 3N6, Kingston, ON, Canada
2
Université de Bordeaux, ISM, UMR 5255, 33405, Talence, France
b
thierry.stoecklin@u-bordeaux.fr
Received:
30
January
2023
Accepted:
2
July
2023
Published online:
31
July
2023
We compute the radiative association (RA) of Cl
with H
and D. We use potential energy and dipole moment surfaces recently tested by a combined theoretical and experimental study of the pre-dissociation spectrum of these complexes. The RA rates are calculated using a quantum approach based on the driven equations formalism and compared with those obtained for similar systems. An indirect comparison with experiment is also discussed using the three body rates measured recently for this system.
Copyright comment Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
© The Author(s), under exclusive licence to EDP Sciences, Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
